Chemical Free Hot Tubs?


Are there “Chemical Free” Spa Water Treatments?


The short answer:

There is no “Chemical Free” system for maintaining and protecting soakers in a hot tub!

Since the first hot tubber slipped into the first barrel to relax and warm their soul, every hot tub sales person has pondered the “chemical free” solution.  Some have even attempted to convince an unwary buyer that such a solution exists. 

Our starting point in hot tub water management is clean – bacteria free – water.  Under Health Canada (and therefore all public health authorities) pathogen control can only be accomplished through the maintenance of a proper active Chlorine (hypochlorous acid-HOCl) or active bromine (hypobromous acid HOBr) level for registered products:

All pool and spa products (chemicals and devices) used to control microorganisms and algae must be registered or scheduled under the Pest Control Products Act. Health Canada reviews applications for registration using scientific information to assess hazards to human health and the environment and determine how well the product works.

Registered or scheduled products carry labels with directions on how to use them, and precautions to minimize hazards to people using the products. Registered products are easily identified. Just look for the five-digit registration number on the front of the package:

*      REGISTRATION NO. 00000 PEST CONTROL PRODUCTS ACT (PCPA); or

*      Reg. No. 00000 PCPA

Scheduled product's label will indicate "Scheduled under The Pest Control Product Act".

Other pool and spa products, like pH adjusters, shock treatment, chlorine neutralizers and devices used only to dispense pool and spa chemicals, do not have to be registered. This is because they do not control disease-causing microorganisms or algae. If you are in doubt about whether a product you are considering is subject to the Pest Control Products Act, please contact the Health Canada Pest Management Information Service.

Avoid unidentified or inadequately labeled products. Use only registered or scheduled products and follow label directions - http://www.hc-sc.gc.ca/cps-spc/pubs/pest/_fact-fiche/pool-spa-piscine/index-eng.php#a8 .

 Any program that does not address this basic requirement is not only dangerous, for the bathers, but illegal to sell in Canada.

In our experience tubers asking for “Chemical Free” systems are really asking for Chlorine and bromine free systems.  In Canada those systems don’t exist.  That said there are some great alternative treatment options that will reduce many of the other hot tub care products.


Botanical products:
These new phosphate free products reduce the pressure on your water and the environment.  The botanicals replace the common synthetics while working with all chlorine or bromine programs. An example of this product line would be the Dazzle Botanical line.


Enzyme products: 
Often presented as  “Chemical Free” they are not and do still require chlorine or bromine to meet Health Canada requirements.  They can, however, greatly reduce your daily and weekly maintenance routines and products.  It is advisable you consult your spa professional on how best to use these products in your application.  Enzyme products have natural softeners that help prevent drying of the skin.  An example of this product line would be SpaMarvel.


Mineral systems:
These are the deluxe hybrid systems that work as easy as the enzymes with the reliability of traditional multi-product programs.  Mineral systems address not only the sanitation concerns but treat the water in such away that the “quality” of the water feel is enhanced.  Natural skin softeners in mineral products results in less skin and membrane irritation.  The big bonus with these systems is the greatly reduced numbers of required maintenance products that hot tubs require when used properly.  The programs work equally well with Chlorine or bromine sanitizers.  Because of their unique method of handling film and oils, users may experience less demand for sanitizers as there is less organic in the water drawing on the oxidizing effects of chlorine (or bromine).  An example of a mineral program is Mineraluxe.


Hydrogen-peroxide:
H2O2 is a strong oxidizer that is occasionally used to treat water.  This product maybe effective but is not a registered sanitizer (under Health Canada) and is very hard to store and handle. 

Hydrogen-peroxide should be stored in a dark and cool area and only handle with adequate eye and skin protection (the fumes are highly toxic and irritating if inhaled).  For spa use it is required that you use 35% hydrogen peroxide (that little bottle under the sink, 3-6%, will have no effect). 

Hydrogen-peroxide has not proven effective to control algae which can cause cloudiness.  If you experience cloudy water you will need to use chlorine.

The pH of Hydrogen peroxide is very low (<3.7).  Besides being an indication of its acidic qualities the low pH also indicates that the pH of you water will tend to drop (eroding your total alkalinity) and as hydrogen peroxide 35% is a liquid , it also indicates the extreme danger of acid burns , if handle improperly.

As a side not large containers of Hydrogen peroxide 35% are controlled for shipping by Transport Canada.


Ionic Mineral  Cartridge Clarifiers:  (silver/copper) These products help to keep to your water clean when used with an approved chlorine sanitizer.  They work by removing small organics that your filter can miss.  In chlorine system they will help remove chloramines which cause irritation and odours.  It is recommended that chlorine (not bromine) be used with these products.  Ion Mineral Cartridges can enhance any of the above programs, improving water quality and security.  An example of this kind of product is Nature 2.


Devices

SALT (chlorine generators):

There is only one device that  has a Health Canada has given a PCPA registration Number for use in hot tubs and that is the ACE Salt chlorine generator by Watkins manufacturing available on HotSpring Spas.  The Ace device produces 5 different oxidizers including active Chlorine and active oxygen.  The expected cell life exceeds 10,000 hours.  These devised need to monitor they own effectiveness and life cycles.  The benefit to this kind of device is the huge reduction of day to day and month to month maintenance.  Most users will also experience longer fill cycles (up to two years between fills)  because the sanitizers and oxidizers are produced in the spa and the by product is simple salt there are no build up of by products associated with power, liquid, and tablet sanitizers.

 UV:
Ultra violet light devices have been around for many years and have found uses in industrial and drinking water treatment applications.  This normally provides the bases of the spa industry claims of reliability.  It is important to note: UV  use in bathing water (swimming and Hot Tub) has never been proven in actual usage applications. and have never been approved, for use as either sanitizers or bacterial/pathogen control devices in bathing applications, by Health Canada or any other federal/third party regulatory agency.  They may provide a clarifying back up to a regular approved sanitizer rĂ©gime.

What are UV systems suppose to do?  UV light expose has been proven to sterilize (not destroy) pathogens in water.  For this to happen the exposure time must be controlled, the source (blub) must be clean, and the bulb must be producing the right wave length.  These three major conditions are difficult to maintain and without regular (daily) pathogen testing you can not be sure the device is working.

It is recommended that the bulb be replaced every year.

Ozone Generators:

The most common form of these devices are the corona discharge style.  There are also a group of UV ozone units (not to be confused with UV sterilizers mentioned above)

A Corona discharge ozone unit produces ozone (O3) by passing air (with O2) through a chamber that is then “Sparked”.  The resulting active electrons form the electric spark facilitates the formation of the O3 molecule.. Ozone is a very unstable molecule so will quickly release the extra oxygen and associated electron effectively oxidizing surrounding organics. 

Ozone is not meant to replace approved sanitizers but will aid in the oxidation of materials in the water freeing your sanitizer to neutralize bacteria and pathogens.

Ozone after it is produced in the CD unit must be mixed into the water.  It is very important how this is accomplished.  If it is injected to quickly (reduced contact time) the ozone will leave the water as a gas (Gas off).  Because ozone is a highly active element if it leaves the water as a gas it can cause damage to spa pillows and covers.  A good ozone system includes a specially designed injector site and a mixing tube to allow the gas bubbles (ozone) to come in contact with a large amount of water while being contained to prevent damage.  By the time the water and ozone mix into the main spa volume there should be very little ozone left and the bubbles that the spa owner will see will be mostly “air”.
In the end the hot tubber will decide what works for them.  However it is strongly recommended they chose a Health Canada register product for their safety, the safety of their guests, and possible liabilities.   Enjoying a hot tub is more than just what's in the water.  Talk to your hot tub profesional and select a program that protects and enhances water safety and quality, then lounge back and ...relax.  VHT.blog 06/03/2013

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