Hot Tubs and Phosphates

Almost all hot tub water care programs include some form of scale and stain control.  This protection is important for the protection of heaters and surfaces of a hot tub.  However evidence is accumulating that suggest this very protection can add to the risk of scale formation. The risk starts with scale and stain products that contain polyphosphonates (HEDP).  HEDP is found in a majority of these control liquids.

We require some calcium on our spa water to control aggressive water leading to equipment failure (including plastics), and uncomfortable conditions for soakers.  There are products that are designed to remove calcium and replaces the calcium with synthetic product that protects the spa surfaces.  These products also contain large amounts of polyphosphates.

Scale forming in a hot tub was most commonly identified as calcium carbonate formed when the calcium in the water combines with carbonates.  The resulting calcium carbonate is less soluble in hot water and begins to precipitate out.  We now recognize that scale can be calcium phosphate formed when orthophosphates combine with calcium resulting in calcium phosphate scale, also insoluble in hot water.

Many of us are familiar with phosphate as a promoter of plant growth  and in the absence of proper sanitizer can promote algae growth.  Phosphates are also a major pollutant to our water systems (rivers and lakes) and should be removed from our hot tub water before draining.

Prevention is the key.
1. Depending on the style of spa treatment you are running, use non-phosphate metal and scale treatments (Dazzle's Stain'n Scale 1 and 2, Mineraluxe are good examples of these new non-phosphate products).
2. Have your water regularly tested for phosphates and maintain levels below 100 ppb.

3. If your phosphate levels exceed 250ppb use a phosphate cleanser (remover) to lower your levels.  THis should be done anytime levels are high an d when draining your spa if your phosphate levels are above recommended levels.

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